Rotational spectrum H19F spin-spin and D-nuclear quadrupole coupling constants and molecular geometry of the sulphur dioxide and hydrogen fluoride dimer

Article


Fillery-Travis, A. and Legon, A. 1986. Rotational spectrum H19F spin-spin and D-nuclear quadrupole coupling constants and molecular geometry of the sulphur dioxide and hydrogen fluoride dimer. Journal of Chemical Physics. 85 (6), pp. 3180-3186. https://doi.org/10.1063/1.451829
TypeArticle
TitleRotational spectrum H19F spin-spin and D-nuclear quadrupole coupling constants and molecular geometry of the sulphur dioxide and hydrogen fluoride dimer
AuthorsFillery-Travis, A. and Legon, A.
Abstract

Through the determination of the spin-spin and quadrupole coupling constants it was possible to determine the dynamics of the hydrogen bonding within this dimer. Specifically the tunneling of the HF molecule between the lone-pairs of the adjacent oxygen atoms of the sulphur dioxide molecule.

Research GroupWork and Learning Research Centre
PublisherAIP Publishing LLC
JournalJournal of Chemical Physics
ISSN0021-9606
Publication dates
Print06 Sep 1986
Publication process dates
Deposited02 Sep 2015
Accepted01 Jan 1986
Output statusPublished
Digital Object Identifier (DOI)https://doi.org/10.1063/1.451829
LanguageEnglish
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