Rotational spectrum H19F spin-spin and D-nuclear quadrupole coupling constants and molecular geometry of the sulphur dioxide and hydrogen fluoride dimer
Article
Fillery-Travis, A. and Legon, A. 1986. Rotational spectrum H19F spin-spin and D-nuclear quadrupole coupling constants and molecular geometry of the sulphur dioxide and hydrogen fluoride dimer. Journal of Chemical Physics. 85 (6), pp. 3180-3186. https://doi.org/10.1063/1.451829
Type | Article |
---|---|
Title | Rotational spectrum H19F spin-spin and D-nuclear quadrupole coupling constants and molecular geometry of the sulphur dioxide and hydrogen fluoride dimer |
Authors | Fillery-Travis, A. and Legon, A. |
Abstract | Through the determination of the spin-spin and quadrupole coupling constants it was possible to determine the dynamics of the hydrogen bonding within this dimer. Specifically the tunneling of the HF molecule between the lone-pairs of the adjacent oxygen atoms of the sulphur dioxide molecule. |
Research Group | Work and Learning Research Centre |
Publisher | AIP Publishing LLC |
Journal | Journal of Chemical Physics |
ISSN | 0021-9606 |
Publication dates | |
06 Sep 1986 | |
Publication process dates | |
Deposited | 02 Sep 2015 |
Accepted | 01 Jan 1986 |
Output status | Published |
Digital Object Identifier (DOI) | https://doi.org/10.1063/1.451829 |
Language | English |
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