Metal size distribution in rainfall and snowmelt-induced runoff from three urban catchments
Article
Lindfors, S., Österlund, H., Lundy, L. and Viklander, M. 2020. Metal size distribution in rainfall and snowmelt-induced runoff from three urban catchments. Science of the Total Environment. 743, p. 140813. https://doi.org/10.1016/j.scitotenv.2020.140813
Type | Article |
---|---|
Title | Metal size distribution in rainfall and snowmelt-induced runoff from three urban catchments |
Authors | Lindfors, S., Österlund, H., Lundy, L. and Viklander, M. |
Abstract | The size distribution of metals transported by urban runoff has implications for treatment type and design, predicting their mobility and evaluating their potential impact on receiving waters. There is an urgent need to better understand the distribution of metals between fractions, particularly those in the sub-dissolved fractions. As a contribution to addressing this need, this study characterises the size distribution of Cd, Cr, Cu, Ni, V and Zn using conventional and novel techniques. Data is presented as event mean concentrations (EMC) of a total of 18 rainfall and snowmelt events at three urban sites. For all studied metals in all events and at all sites, the contribution of the truly dissolved fraction made a greater contribution to the total concentrations than the colloidal fraction. Truly dissolved Cd and Zn concentrations contributed (on average) 26% and 28% respectively, of the total EMCs with truly dissolved Cu and Ni contributing (on average) 18%. In contrast, only 1% (V) and 3% (Cr) were identified in the truly dissolved fraction. The greatest contribution of truly dissolved Cd, Cu and Zn concentrations (relative to total oncentrations) were reported during rainfall events. However, no seasonal differences were identified and differences between the sites regarding the EMCs distribution by fractions were not at a statistically significant level (p N 0.05) for any metal or event. The loads of truly dissolved and colloidal metals did not follow the patterns of particulate metal loads indicating particulates are not the main source of subdissolved metals. The data suggests that ultrafiltration as a treatment technique would not efficiently mitigate the risks posed by metals to receiving water cologies |
Keywords | Urban runoff; Size fractionation; Dissolved metals; Truly dissolved; Colloids; Ultrafiltration |
Publisher | Elsevier |
Journal | Science of the Total Environment |
ISSN | 0048-9697 |
Electronic | 1879-1026 |
Publication dates | |
Online | 08 Jul 2020 |
15 Nov 2020 | |
Publication process dates | |
Deposited | 26 Apr 2021 |
Accepted | 06 Jul 2020 |
Output status | Published |
Publisher's version | License File Access Level Open |
Copyright Statement | © 2020 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). |
Digital Object Identifier (DOI) | https://doi.org/10.1016/j.scitotenv.2020.140813 |
Language | English |
https://repository.mdx.ac.uk/item/89586
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