Sorption behaviours and transport potentials for selected pharmaceuticals and triclosan in two sterilised soils

Article

Revitt, D., Balogh, T. and Jones, H. 2015. Sorption behaviours and transport potentials for selected pharmaceuticals and triclosan in two sterilised soils. Journal of Soils and Sediments. 15 (3), pp. 594-606. https://doi.org/10.1007/s11368-014-1025-y
TypeArticle
TitleSorption behaviours and transport potentials for selected pharmaceuticals and triclosan in two sterilised soils
AuthorsRevitt, D., Balogh, T. and Jones, H.
Abstract

Purpose: Pharmaceuticals and personal care products (PPCPs) are emerging environmental pollutants, which in addition to direct deposition processes, can find their way into surface soils through the agricultural application of sewage sludge and irrigation practices using contaminated wastewater. Therefore, it is important to assess the extent to which soils are able to retain PPCPs and to prevent their downward migration towards groundwaters. Materials and methods: To further our understanding in this area, batch sorption experiments and artificial rainwater leaching experiments have been performed using five compounds (bezafibrate, carbamazepine, chloramphenicol, diclofenac and triclosan) possessing a range of physicochemical properties in two soils with differing acidities and organic carbon contents.
Results and discussion: The determined Koc values for triclosan and diclofenac consistently demonstrated their lower potential mobilities in both soils. The predicted high mobility of chloramphenicol is supported by its efficient leaching potential (89-100%) in both soils whereas bezafibrate, diclofenac and carbamazepine demonstrate slightly lower affinities for the leachate (61-96%) for soil A and are strongly retained (>99%) by soil B. The amount of PPCP in the leachate, the rate of leaching and the depth of soil penetration are explained in terms of the soil characteristics and the properties of the individual PPCPs (such as solubility and pKa) with soil organic content being shown to be a critical factor controlling the ability of a soil to retain a PPCP in the surface layers.
Conclusions: The findings contribute to the scientific knowledge required by practitioners and regulators as they consider future sub-soil contamination by PPCPs and subsequent possible threats to groundwater resources and surface water habitats.

KeywordsBatch sorption experiments; Distribution coefficients; Leaching potentials; Pharmaceuticals and personal care products; Soil depth distributions; Soil mobilities
PublisherSpringer
JournalJournal of Soils and Sediments
ISSN1439-0108
Electronic1614-7480
Publication dates
Online23 Nov 2014
Print31 Mar 2015
Publication process dates
Deposited10 Mar 2015
Submitted17 Jun 2014
Accepted06 Nov 2014
Output statusPublished
Accepted author manuscript
Copyright Statement

This is a post-peer-review, pre-copyedit version of an article published in Journal of Soils and Sediments. The final authenticated version is available online at: http://dx.doi.org/10.1007/s11368-014-1025-y

Digital Object Identifier (DOI)https://doi.org/10.1007/s11368-014-1025-y
Web of Science identifierWOS:000349605100011
LanguageEnglish
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