Photoluminescence characteristics of ZnO doped with Eu3+ powders

Article

Fang, T., Chang, Y., Ji, L., Prior, S., Water, W., Chen, K., Fang, C., Fang, C. and Shen, S. 2009. Photoluminescence characteristics of ZnO doped with Eu3+ powders. Journal of physics and chemistry of solids. 70 (6), pp. 1015-1018. https://doi.org/10.1016/j.jpcs.2009.05.012
TypeArticle
TitlePhotoluminescence characteristics of ZnO doped with Eu3+ powders
AuthorsFang, T., Chang, Y., Ji, L., Prior, S., Water, W., Chen, K., Fang, C., Fang, C. and Shen, S.
Abstract

In this work, we have investigated the photoluminescence spectra of europium-doped zinc oxide crystallites prepared by a vibrating milled solid-state reaction method. X-ray diffraction, scanning electron microscopy, luminescence spectra and time-resolved spectra analysis were used to characterize the synthetic ZnO:Eu3+ powders. XRD results of the powders showed a typical wurtzite hexagonal crystal structure. A second phase occurred at 5 mol% Eu2O3-doped ZnO. The 5D0–7F1 (590 nm) and 5D0–7F2 (609 nm) emission characteristics of Eu3+ appeared after quenching with more than 1.5 mol% Eu2O3 doping. The Commission Internationale d’Eclairage (CIE) chromaticity coordinates of a ZnO:Eu3+ host excited at λex=467 nm revealed a red-shift phenomenon with increase in Eu3+ ion doping. The lifetime of the Eu3+ ion decreased as the doping concentration was increased from 1.5 to 10 mol%, and the time-resolved 5D0→7F2 transition presents a single-exponential decay behavior.

PublisherPergamon (Elsevier)
JournalJournal of physics and chemistry of solids
ISSN0022-3697
Publication dates
PrintJun 2009
Publication process dates
Deposited15 Oct 2009
Output statusPublished
Digital Object Identifier (DOI)https://doi.org/10.1016/j.jpcs.2009.05.012
LanguageEnglish
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